Waste.net
Recovery 2.0
Mixed Solid Wastes

recovery2.0
Solid Waste Recovery
Key Points
Flow Pathway Options

Solid Fractions
Gas Recovery       Hi-Temp Refining

Mixed Plastic Wastes
Brine & Waste Water
solid waste recovery

Overview
The Recovery 2.0 Thermal Reduction process converts mixed wastestreams on a Mass Balance basis into two intermediate process pathways consisting of solid and gaseous phase fractions.

The solid residual fraction (after SRF thermal reduction) may only account for less than 5% of the total output depending on the consistency of the source feedstock. The gaseous fraction generated from Solid Recovered Fuel (SRF) sourced from typical Municipal Solid Waste (MSW) may range from 75% to 95% of the output.
The typical moisture content of SRF may range from 15 to 30 % of the weight and food waste can contain greater that 50 % water. The H2O content is converted into and included in the gaseous fraction.
The gas fraction typically expands from 1,00 to 2,000 times the volume from the original waste feedstock.

The challenge in the gas phase processing is managing the sheer volume of gas generated with the range of temperatures and pressures. Special precautions are required for the handling of those fractions that are toxic or are flammable in nature.

The typical historic Thermal Reduction method of Waste Recovery utilizes various forms of combustion. The shortfall of these systems has been the under management of emissions or the lack of accounting of total waste in and total product outputs.
Traditional energy from waste systems tend to focus mostly on the solid ash content and limiting toxic emission levels, but the balance of the largely unaccounted for materials are released into the open atmosphere.
The Recovery 2.0 process embraces the Mass Balance approach of managing the total input and output equilibrium.

Combustion Free options are available. By utilizing a combination of novel and passive approaches to resource recovery that are traditionally deemed as less efficient or not energy dense, we may be able to achieve neutral emission goals with Short Cycle Regeneration methods.

Hydrocarbon Pipeline
click to expand

Hydrocarbon Pipeline
Emissions generated from the thermal reduction unit are vented and contained within a Hydrocarbon working fluid pipeline. The pipeline feeds the Hot Gas Refining process where the product charged working fluids are segregated and converted into the desired output products.
If the chosen primary energy source produces Hydrocarbon Emissions, those emissions may be merged directly into the product stream pipeline and fed into the Hot Gas Refining process.

Unlike traditional incineration or Energy from waste approaches, The Recovery 2.0 process captures what would be flue gas and cooling tower emissions and converts them directly into product outputs. This process extracts value from the recovered resources while eliminating the undesirable emissions.

Waste Recovery Process       -   Mixed Solid Wastes

      Pathway Flow & Options
                  - Recovery 2.0 Overview
                            - Mass Balance
                            - Carbon Reality
                            - Combustion Free Concepts

                  - Mixed Waste Feedstocks
                            - Solid Recovered Fuel (SRF)
                            - Hydrocarbon Wastes
                            - Complex Materials
                            - Sludges and Residues

                  - Thermal Reduction Process
                            - Gas Phase Processing
                            - Water Recovery

                  - Solid Fraction
                            - Elemental Carbon
                            - Inert Fraction
                                    - Mineral Recovery
                                    - Metal Recovery

          Energy Sources
                  - Heat Sources
                  - Electricity

                  - Energy Storage
                  - Short Cycle Regeneration
                  - Energy Pathways

Waste Recovery Process           - Summary


Waste Stream Pathway

Mixed Wastes
Waste Recovery is an energy intense process, a sustainable approach to treat waste as a resource with a goal of recovering valuable materials while generating no undesirable emissions with a net zero energy processing cost. The Novel Approach objective is to harvest sufficient concentrated solar energy to sustain around the clock operations.
While not attempting to address the issues of grid scale energy storage, we find ourselves focusing on the challenges of intermittent off hour operating when choosing solar as a primary energy source.

CHNOPS - Carbon, Hydrogen, Nitrogen, Oxygen, Phosphorus, Sulfur, these six elements make up 98% of living matter on Earth.
Typical Hydrocarbon Waste Materials generated from Municipal Solid Waste (MSW) in the form of Solid Recovered Fuel (SRF) contain complex Hydrocarbon molecules or long chain polymers. The gas phase of the SRF thermal reduction process produces a mix of Carbon, Hydrogen and Oxygen typically made up of approximately 95% of the volume with the remainder of all other gases and vapors combined totaling less than 5%.

The thermal reduction process breaks these into shorter chains or monomers and some prefer this partial decomposition in order to selectively output a desired product. Adding additional heat, dwell time or pressure to the thermal reduction process will promote a further or more complete breakdown into simple elements. For example hydrocarbon mixes may be reduced to produce elemental carbon and Hydrogen.

Hydrogen has a natural affinity to bind with Oxygen to form the stable compound of water. Please also note that common solid wastes referred to as dry wastes contain a moisture content, that natural water content along with the combination of wet organic materials add to the total yield of H2O.

solid recovery fractions.gif

Solid Fraction
The Thermal Reduction Process generates an intermediate stage output in the form of a solid fraction. This solid fraction is comprised largely of Elemental Carbon and a mixed Inert Fraction.

Elemental Carbon Fraction
Depending on the blend of raw input, the content in a common SRF feedstock will yield carbon as typically the most abundant component of the solid fraction. Recovered Elemental Carbon is referred to by a variety of names by numerous different parties, but terms such as biochar or carbon black are attempts to define the same element.

Inert Fraction
The Mixed inert materials consist of a Mineral content and directly recoverable Metals and a mix of strategic or critical Trace Residue materials. Some of these materials may require High Temperature Refining or other specialty treatment to facilitate selective recovery.

BioSoilds Refining & Treatment

Summary
While the resource recovery of Mixed Solid Wastes must deal with the management of all the complex elements contained, the main focus of the Recovery 2.0 efforts will always revolve around the 3 predominant elements of Carbon, Hydrogen, Oxygen and the energy required in their transition.

Mixed Hydrocarbon may be reduced to produce elemental carbon and Hydrogen.
Hydrogen has a natural affinity to bind with Oxygen to form the stable compound of water.

Thermal Reduction is dependant on heat as a driving energy force but it is in units of electricity that are universally used as a common denominator to calculate process requirements and efficiency.

              Recovery 2.0 = Carbon + Water + Electricity

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A Novel Recovery Approach

Novel Approach
incoming waste stream       Mixed Waste
Hot Gas Refining       Bio-Refining

Desalination       Brine     Water Purification
Resource Recovery

Bio-Refining       High Temperature Refining
Hot Gas Refining


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